physics - Pauli matrices

The Pauli matrices are a set of 2 × 2 complex Hermitian matrices developed by Pauli. They are:

$\sigma_1 = \begin{pmatrix} 0&1\\ 1&0 \end{pmatrix}$

$\sigma_2 = \begin{pmatrix} 0&-i\\ i&0 \end{pmatrix}$

$\sigma_3 = \begin{pmatrix} 1&0\\ 0&-1 \end{pmatrix}$

The determinants and traces of the Pauli matrices are:

$\begin{matrix} \det (\sigma_i) &=& -1 & \\ \operatorname{Tr} (\sigma_i) &=& 0 & \quad \hbox{for}\ i = 1, 2, 3 \end{matrix}$

The Pauli matrices obey the following commutation and anticommutation relations:

$\begin{matrix} [\sigma_i, \sigma_j] &=& 2 i\,\epsilon_{i j k}\,\sigma_k \\ \{\sigma_i, \sigma_j\} &=& 2 \delta_{i j} \cdot I \end{matrix}$

where ε_ijk is the Levi-Civita symbol, δ_ij is the Kronecker delta, and I is the identity matrix. Aboves relations can be verified using

$\sigma_i \sigma_j = i \epsilon_{ijk} \sigma_k + \delta_{ij} \cdot I$ .

The above commutation relations are similar to those of the Lie algebra su(2), and indeed su(2) may be identified with the Lie algebra of all real linear combinations of i times the Pauli matrices iσ_j, i.e. with the anti-Hermitian 2×2 matrices with trace 0. In this sense, the Pauli matrices generate su(2). As a result, iσ_j can be seen as infinitesimal generators of the corresponding Lie group SU(2).

The Lie algebra su(2) is isomorphic to the Lie algebra so(3), which corresponds to the Lie group SO(3), the group of rotations in three-dimensional space. In other words, iσ_j are a realization (and, in fact, the lowest-dimensional realization) of infinitesimal rotations in three-dimensional space.

In quantum mechanics, iσ_j represent the generators of rotation acting on non-relativistic particles with spin ½. The state of the particles are represented as two-component spinors, which is the fundamental representation of SU(2). An interesting property of spin ½ particles is that they must be rotated by an angle of 4π in order to return to their original configuration. This is due to the fact that SU(2) and SO(3) are not globally isomorphic, even though their infinitesimal generators su(2) and so(3) are isomorphic. SU(2) is actually a "double cover" of SO(3), meaning that each element of SO(3) actually corresponds to two elements in SU(2). Also useful in the quantum mechanics of multiparticle systems, the general Pauli group G_n is defined to consists of all n-fold tensor products of Pauli Matrices.

Together with the identity matrix I (which is sometimes written as σ₀), the Pauli matrices form a basis for the real vector space of 2 × 2 complex Hermitian matrices. This basis is equivalent to the quaternions, and when used as the basis for the spin-½ rotation operator is the same as the corresponding quaternion rotation representation.